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Bioavailability is a major hurdle for glutathione

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The catalytic glutamate residue E 115 accepts a proton from the -glutamyl group of the substrate, initiating a nucleophilic attack by the amine on the amide carbon atom

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On the other hand, if the presence of cyanotoxin is detected in Spirulina products, gastrointestinal effects such as severe hypercalcemia, vomiting, nausea, and diarrhea have been reported (115)