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C-terminus is free acid (-OH) rather than amide (-NH2) Contains D-Phe (same non-natural stereochemistry as MT-II) N-terminal: acetylated

The three amino acids mediate its anti-inflammatory activity at the end of whats called the N terminal:lysine-proline-valine

262 In gout, the release of IL-1 mediated by inflammasomes triggers a significant inflammatory response characterized by vasodilation and rapid recruitment of neutrophils to the site of crystal deposition, thereby driving acute inflammatory episodes

Glutathione is well known as an anti-oxidant agent, providing a major line of defense against oxidative and other forms of stress, largely as a cofactor for the glutathione peroxidase and S-transferase enzyme families (7-10)